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Organometallic Radical-Adducts of Fullerenes C60, 70, and Single-Walled Carbon Nanotubes Derived from (Cyclopentadienyl)molybdenumtricarbonyl Dimer

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Abstract:

Interaction of the metal-centered free radicals [CpMo(CO)3] generated photochemically from the corresponding dimer [CpMo(CO)3]2 with fullerenes C60, C70, or single-walled carbon nanotubes in toluene results in the radical-adducts investigated by using TGA, ESR, Raman and X-ray Photoelectron spectroscopy. Comparison was made with the chromium analogues previously studied.

Keywords: (CYCLOPENTADIENYL)MOLYBDENUMTRICARBONYL DIMER; C70; ESR SPECTROSCOPY; FULLERENES C60; MOLYBDENUM-CENTERED FREE RADICAL; RADICAL-ADDUCTS; RAMAN; SINGLE-WALLED CARBON NANOTUBES; X-RAY PHOTOELECTRON SPECTROSCOPY

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2007.338

Publication date: April 1, 2007

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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