Organometallic Radical-Adducts of Fullerenes C60, 70, and Single-Walled Carbon Nanotubes Derived from (Cyclopentadienyl)molybdenumtricarbonyl Dimer
Abstract:Interaction of the metal-centered free radicals [CpMo(CO)3]• generated photochemically from the corresponding dimer [CpMo(CO)3]2 with fullerenes C60, C70, or single-walled carbon nanotubes in toluene results in the radical-adducts investigated by using TGA, ESR, Raman and X-ray Photoelectron spectroscopy. Comparison was made with the chromium analogues previously studied.
Keywords: (CYCLOPENTADIENYL)MOLYBDENUMTRICARBONYL DIMER; C70; ESR SPECTROSCOPY; FULLERENES C60; MOLYBDENUM-CENTERED FREE RADICAL; RADICAL-ADDUCTS; RAMAN; SINGLE-WALLED CARBON NANOTUBES; X-RAY PHOTOELECTRON SPECTROSCOPY
Document Type: Research Article
Publication date: April 1, 2007
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