Synthesis of Allyl-Bearing Dendrimers with a Resorcinarene Core and Their Supramolecular Complexes with Fullerene C60

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Abstract:

Dendritic branches of poly(arylether) with peripherial allyl chains have been attached to a resorcinarene core. Dendrimers of first, second, and third generation were synthesized. Viability to form supramolecular complexes with fullerene C60 was studied with three dendrimers of first, second, and third generation. All the compounds were characterized by 1H, 13C NMR, FTIR, UV-vis spectroscopy, MALDI-TOF, FAB+ mass spectra, and elemental analysis. Strong , C H–, and n interactions between the dendrimers and the fullerene C60 were detected in the supramolecular complexes by UV-vis, FTIR, and 13C CP-MAS NMR.

Keywords: ALLYL; DENDRIMERS; FULLERENE C60; POLY(ARYL ETHER); RESORCINARENE; SUPRAMOLECULAR COMPLEXES

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2007.316

Publication date: April 1, 2007

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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