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Radical Reactions of [60]Fullerene Mediated by Manganese(III) Acetate Dihydrate

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Abstract:

Mn(OAc)3 · 2H2O is an excellent reagent to promote free radical reactions of C60. C60 reacted with various methylene active compounds, methyl ketones, -enamino carbonyl compounds, carboxylic acid derivatives, and diallylamines in the presence of Mn(OAc)3 · 2H2O to afford singly-bonded fullerene dimers, 1,4-bisadducts and 1,16-bisadducts of C60, C60-fused dihydrofuran derivatives, methanofullerenes, C60-fused pyrroline derivatives, C60-fused lactone derivatives, and C60-fused pyrrolidine derivatives. Mn(OAc)3 · 2H2 O was successfully employed to transform ArC60-H into ArC60-OAc.

Keywords: RADICAL REACTIONS; [60]FULLERENE MANGANESE(III) ACETATE DIHYDRATE

Document Type: Review Article

DOI: http://dx.doi.org/10.1166/jnn.2007.305

Publication date: April 1, 2007

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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