Skip to main content

Single Layer Polycrystalline ZnO–Al2O3 Nanocomposite Thin Films: Optical and Electrical Properties

Buy Article:

$113.00 plus tax (Refund Policy)

Abstract:

Nanometric size dependent optical absorption coefficients, dispersive nature of the dielectric constants and ac conductivity are observed for the single layer ZnOx(Al2O3)1−x (x = 0.20 and 0.50) nanocomposites thin films. The sol–gel prepared thin films with thickness approximately 119 nm, contains randomly dispersed ZnO nanocrystallites in the Al2O3 matrix. Transmission electron microscopy (TEM) and atomic force microscopy (AFM) revealed homogeneous distributions of the nanoparticles in the matrix. The shifting and broadening of the optical absorption peaks to the lower wavelength region at higher annealing temperatures was analyzed in order to relate the particle–particle interactions and the sizes of the dispersed nanoparticles in the matrix. AC impedance spectroscopy in the frequency range of 500 Hz to 5 MHz was measured at room temperature (300 K), 325 K, 395 K, and 450 K. The dielectric relaxations in each case were found to be of Cole–Cole type. The semicircular pattern of the ac capacitance in the complex plane showed contributions from the grain and grain boundary subject to concentration of ZnO in the matrix. The appearance of the negative capacitance at higher frequency was also analyzed.

Keywords: AC CONDUCTIVITY; BURSTEIN-MOSS SHIFT; NANOCOMPOSITE; SOL-GEL; THIN FILM

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2007.432

Publication date: July 1, 2007

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • Ingenta Connect is not responsible for the content or availability of external websites
asp/jnn/2007/00000007/00000007/art00029
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more