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pH Sensitive Organic–Inorganic Layered Nanomaterials by Self-Assembly of Indigocarmine Between the Inorganic Layers

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New pH sensitive organic–inorganic intercalation compounds having different interlayer spacing were prepared. Zn–Al layered double hydroxide (LDH)is an anion exchangeable inorganic layered compound whose interlayer spacing is 0.76 nm. In the reactions of indigocarmine (IDC) with the calcined Zn–Al LDH at pH = 7 (LDH-IDC7), interlayer spacing increased to 2.25 nm. The interlayer spacing of LDH-IDC7 decreased to 1.89 nm by the treatment in basic solution. In the reaction of IDC with the calcined Zn–Al LDH at pH = 10 (LDH-IDC10), interlayer spacing of the intercalation compounds was 1.89 nm. The interlayer spacing of these intercalation compounds was changed reversibly by the treatments in acidic or basic solution.


Document Type: Short Communication

DOI: http://dx.doi.org/10.1166/jnn.2006.203

Publication date: June 1, 2006

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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