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Heterogeneous Photocatalytic Degradation of Methanol over Uranyl-Anchored Nanoporous MCM-41 and MCM-48

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Abstract:

The vapor-phase photodegradation of methanol to carbon dioxide was carried out over uranyl-anchored nanoporous MCM-41 and MCM-48 hosts (designated as UO2+2/MCM-41 and UO2+2/MCM-48, respectively) under simulated light and ambient conditions. Preliminary results indicate that the photoactivity of the latter is considerably decreased as compared to the former due to the presence of a smaller fraction of photoactive uranyl (UO2+2) ions in UO2+2/MCM-48.

Keywords: HETEROGENEOUS PHOTOCATALYSIS; MCM-41; MCM-48; METHANOL OXIDATION; NANOPOROUS MATERIAL; URANIUM OXIDE; URANYL

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2006.226

Publication date: June 1, 2006

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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