Skip to main content

Complexes of Carbon Nanotubes with Selected Carotenoids

Buy Article:

$113.00 plus tax (Refund Policy)

Abstract:

As proven by the UV-VIS, micro-Raman spectroscopies, differential scanning calorimetry, -carotene, lycopene, retinoic acid, and retinol adsorbed on the surface of single-walled carbon nanotubes (SWCNT) form electron donor–acceptor (EDA) complexes. The rate of the adsorption of carotenoids is estimated as the rate of decrease in their concentration in solution followed the exponential curve equation. The rate of the adsorption decreased with the chain length of the guest capable sorption on the surface and steric effect of the terminals in the -carotene was also essential. Also, increase in the polarity of the functional groups expressed, for instance, in Taft * substituent constants had its impact. The HyperChem 7 followed by Gaussian 03 computations revealed that the inclusion SWCNT–carotenoid complexes were more stable than corresponding surface complexes. In the surface complexes carotenoids acted as donors in respect to SWCNT whereas in the inclusion complexes they were acceptors.

Keywords: BETA-CAROTENE; INCLUSION COMPLEXES; LYCOPENE; RETINOIC ACID; RETINOL; SINGLE-WALLED CARBON NANOTUBES; SURFACE COMPLEXES

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2005.410

Publication date: December 1, 2005

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • ingentaconnect is not responsible for the content or availability of external websites
asp/jnn/2005/00000005/00000012/art00023
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more