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Nanocrystallization of Ferroelectric Strontium Bismuth Vanadium Niobate in Lithium Tetraborate Glasses

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Abstract:

Transparent glass samples in (100−3x) (Li2O–2B2O3)−x(SrO–Bi2O3–0.7Nb2O5–0.3V2O5) (10 ≤x≤60, in molar ratio) system have been fabricated via conventional melt-quenching technique. The as-quenched samples, of all the compositions under study have been confirmed to be amorphous, by X-ray powder diffraction (XRD) studies. Differential thermal analysis (DTA) was employed to confirm the glassy nature of the as-quenched glasses. Glass composites comprising vanadium doped strontium bismuth niobate nanocrystallites were obtained by controlled heat-treatment of the as-quenched glasses at 783 K for 6 h. Perovskite SrBi2(Nb0.7V0.3)2O9− phase formation was found to be preceded by an intermediate fluorite phase which was established via XRD and transmission electron microscopy (TEM). The dielectric constants (r) of the as-quenched glasses as well as the glass nanocrystal composites decreased with increase in frequency (100 Hz–10 kHz) at 300 K. Interestingly, the dielectric constant of the glass nanocrystal composite (heat-treated at 783 K/6 h) undergoes a maximum in the vicinity of the crystallization temperature of the host glass (Li2B4O7) reaching an anomalously high value (≈106) at 800 K. Different dielectric mixture formulae were employed to rationalize the dielectric properties of the glass nanocrystal composite. The optical transmission properties of these glass nanocrystal composites were found to have strong compositional dependence.

Keywords: DIELECTRIC PROPERTIES; GLASS NANOCRYSTAL COMPOSITE; LITHIUM BORATE; STRONTIUM BISMUTH VANADIUM NIOBATE; X-RAY DIFFRACTION

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2005.415

Publication date: 2005-12-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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