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Sol–Gel Synthesis of Luminescent InP Nanocrystals Embedded in Silica Glasses

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Abstract:

III–V semiconductor nanocrystals rarely exist as spherical inclusions inside glasses, due to difficulties during their preparation, such as high toxic reagents or fast oxidation under usual glass technology temperatures. In this letter a sol–gel method for synthesis of InP nanocrystals embedded in silica glasses was described. Gels were synthesized by hydrolysis of a complex solution of Si(OC2H5)4, InCl3 ·4H2O, and PO(OC2H5)3. Then, the gels were heated at 600 °C in the presence of H2 gas to form fine cubic InP crystallites. Raman spectrum showed an InP longitudinal-optic mode (342 cm−1) and a transverse-optic mode (303 cm−1). The size of InP nanocrystals was found to be from 2 to 8 nm in diameter by transmission electron microscopy. A strong photoluminescence with a peak at 856 nm was observed from InP nanocrystals embedded in silica glasses. The results suggest that it might be possible to synthesize other III–V semiconductor nanocrystals embedded in silica glasses through the sol–gel process.

Keywords: AND RAMAN SPECTRUM; INP NANOCRYSTALS; INP/SIO2 NANOCOMPOSITIONS; PHOTOLUMINESCENCE; SOL-GEL METHOD

Document Type: Short Communication

DOI: https://doi.org/10.1166/jnn.2005.176

Publication date: 2005-10-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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