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Interactions of Single-Walled Carbon Nanotubes with Monosaccharides

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Abstract:

Closed-end single-walled carbon nanotubes were wetted in aqueous solutions of monosaccharides, forming weak surface complexes, as proven by the estimation of the content of monosaccharides in complexes isolated from aqueous solutions. The complexation was confirmed by micro-Raman spectroscopy. The Gaussian 03 (Molecular Mechanics UFF method) computations of total energy of the single-walled carbon nanotube–monosaccharides inclusion and surface complexes showed that inclusion complexes should be more stable than corresponding surface complexes. Computed total energies for particular complexes pointed to a lack of preferences for the formation of complexes with either α- or -tautomers and either pyranoses or furanoses. The forms preferred in the formation of the surface complexes usually differ from these favored in the formation of the inclusion complexes.

Keywords: INCLUSION COMPLEXES; MONOSACCHARIDE; SINGLE-WALLED CARBON NANOTUBES; SURFACE COMPLEXES; UFF MOLECULAR MECHANICS

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2005.054

Publication date: 2005-03-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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