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Nanoparticle Size-Dependent Lowering of Temperature for Phase Transition from In(OH)3 to In2O3

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Phase transformation of In(OH)3 to In2O3 has been studied as a function of nanoparticle size without any alteration of nanoparticle size during transformation. Chemically capped In(OH)3 nanoparticles having sizes of 15, 11, and 8 nm transform to In2O3 at temperatures of 285, 272, and 255°C, respectively. This first-time unambiguous observation of size-dependent lowering of transformation temperature represents a thermodynamic characteristic of the nanoparticle system. The results have been explained in terms of a lower cohesive energy of surface atoms and an increase in surface-to-volume ratio with a decrease in nanoparticle size.


Document Type: Research Article


Publication date: 2005-03-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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