@article {Walter:2004:1533-4880:121, title = "Optical Visualization of Polymer-Polymer Interactions", journal = "Journal of Nanoscience and Nanotechnology", parent_itemid = "infobike://asp/jnn", publishercode ="asp", year = "2004", volume = "4", number = "1-2", publication date ="2004-01-01T00:00:00", pages = "121-124", itemtype = "ARTICLE", issn = "1533-4880", eissn = "1533-4899", url = "https://www.ingentaconnect.com/content/asp/jnn/2004/00000004/f0020001/art00016", doi = "doi:10.1166/jnn.2004.227", keyword = "POLYELECTROLYTES, NANOPARTICLE, SURFACE-ENHANCED ABSORPTION", author = "Walter, H. and Bauer, G.", abstract = "Surface-enhanced absorption (SEA) has been used to monitor interactions of biomolecules and to observe structural changes of polymers. Such interactions of biomolecules are of interest in high-throughput screening and diagnostics. The structural changes of synthetic polymers can be exploited in optical sensorics. Based on SEA we have developed a technique that enables us to transfer the interaction of polyelectrolytes between two flat, solid surfaces into a visible color change, exploiting nanoscopic metal clusters. The polyelectrolytes are coated onto electrochemically oxidized aluminum, glass, and polycarbonate substrates. The change of surface color is monitored with a flat-bed scanner, and the interactions are analyzed kinetically. The results are interpreted with regard to adhesion, surface tension, electrostatic interactions, and miscibility. ", }