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Optical Visualization of Polymer-Polymer Interactions

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Abstract:

Surface-enhanced absorption (SEA) has been used to monitor interactions of biomolecules and to observe structural changes of polymers. Such interactions of biomolecules are of interest in high-throughput screening and diagnostics. The structural changes of synthetic polymers can be exploited in optical sensorics. Based on SEA we have developed a technique that enables us to transfer the interaction of polyelectrolytes between two flat, solid surfaces into a visible color change, exploiting nanoscopic metal clusters. The polyelectrolytes are coated onto electrochemically oxidized aluminum, glass, and polycarbonate substrates. The change of surface color is monitored with a flat-bed scanner, and the interactions are analyzed kinetically. The results are interpreted with regard to adhesion, surface tension, electrostatic interactions, and miscibility.

Keywords: NANOPARTICLE; POLYELECTROLYTES; SURFACE-ENHANCED ABSORPTION

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2004.227

Publication date: January 1, 2004

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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