Clustering Effects on Discontinuous Gold Film NanoCells
Authors: Jorge M. Seminario; Yuefei Ma; Luis A. Agapito; Liuming Yan; Roy A. Araujo; Sridhar Bingi; Nagendra. S. Vadlamani; Krishna Chagarlamudi; Tangali S. Sudarshan; Michael L. Myrick; Paula E. Colavita; Paul D. Franzon; David P. Nackashi; Long Cheng; Yuxing Yao; James M. Tour
Source: Journal of Nanoscience and Nanotechnology, Volume 4, Number 7, September 2004 , pp. 907-917(11)
Publisher: American Scientific Publishers
Abstract:
Reproducible negative differential resistance (NDR)-like switching behavior is observed in NanoCells. This behavior is attributed to the formation of filaments and clusters between the discontinuous gold films. Control experiments are performed by self-assembly of insulating molecules between the gold islands and conducting molecules on these islands. Additional control experiments are performed by removing the filaments and clusters between islands using a piranha bath. The results are consistent with theoretical predictions and extend the domain of molecular electronics based in organic molecules to include nanosized clusters as active units. This facilitates a scenario where synthetically accessible organic molecules, with defined characteristics, can be adjusted by metallic nanoclusters as an in situ fine-tuning element, able to compensate for the lack of addressing in the nanosize regime.Keywords: NEGATIVE DIFFERENTIAL RESISTANCE; NANOCELL; CLUSTERING; FILAMENTARY FORMATION; DISCONTINUOUS GOLD FILM; INTERLINKING MOLECULE; SELF-ASSEMBLING; AB INITIO; MOLECULAR; DYNAMICS; DENSITY FUNCTIONAL THEORY; NANOTECHNOLOGY; MOLECULAR ELECTRONICS; NANOELECTRONICS
Document Type: Research article
DOI: http://dx.doi.org/10.1166/jnn.2004.104
Publication date: 2004-09-01
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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- By this author: Jorge M. Seminario ; Yuefei Ma ; Luis A. Agapito ; Liuming Yan ; Roy A. Araujo ; Sridhar Bingi ; Nagendra. S. Vadlamani ; Krishna Chagarlamudi ; Tangali S. Sudarshan ; Michael L. Myrick ; Paula E. Colavita ; Paul D. Franzon ; David P. Nackashi ; Long Cheng ; Yuxing Yao ; James M. Tour

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