Role of Interfacial Effects in Carbon Nanotube/Epoxy Nanocomposite Behavior

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The interfacial effects are critical to understand the nanocomposite behavior based on polymer matrices. These effects are dependent upon the morphology of carbon nanotubes, the type of used polymer and the processing technique. Indeed, we show that the different parameters, as the eventual surfactant use, the ultrasonic treatment and shear mixing have to be carefully examined, in particular, for nanotube dispersion and their possible alignment.

A series of multiwalled nanotubes (MWNT) have been mixed with a regular epoxy resin under a controlled way to prepare nanocomposites. The influence of nanotube content is examined through helium bulk density, glass transition temperature of the matrix and direct current electrical conductivity measurements. These results, including the value of the percolation threshold, are analyzed in relationship with the mesostructural organization of these nanotubes, which is observed by standard and conductive probe atomic force microscopy (AFM) measurements. The wrapping effect of the organic matrix along the nanotubes is evidenced and analyzed to get a better understanding of the final composite characteristics, in particular, for eventually reinforcing the matrix without covalent bonding.


Document Type: Research Article


Publication date: September 1, 2004

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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