Plasmon Absorption of Gold Nanoparticles in Linear Polymer Solutions
Authors: Chih-Ching Huang; Yu-Fen Huang; Huan-Tsung Chang
Source: Journal of Nanoscience and Nanotechnology, Volume 4, Number 6, July 2004 , pp. 622-627(6)
Publisher: American Scientific Publishers
Abstract:Gold nanoparticles (GNPs) are stable in a number of linear polymer solutions, including poly(vinyl alcohol), poly(N-vinyl-2-pyrrolidone), hydroxyethyl cellulose, and poly(ethylene oxide) (PEO). Of these, PEO, with a wide range of molecular mass (from 0.3 to 8 MDa), is particularly attractive for exploring the interaction between the GNPs and polymer molecules. We have found that the colors of the GNPs are significantly different in PEO solutions at concentrations below and above entanglement threshold concentration (*), which allows one to determine * values for different sizes of PEO from the inflection points of the plots of the absorbance at 600 nm against the concentration of PEO. The * values are close to those obtained by the viscosity measurements, showing the usefulness of this simple method. Transmission electron microscopy images have confirmed that the change in the absorbance is due to the aggregation and/or agglomeration of the GNPs in PEO solutions.
Document Type: Research article
Publication date: 2004-07-01
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Terms & Conditions
- ingentaconnect is not responsible for the content or availability of external websites