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The Substituent Effect on Nonlinear Current Voltage Characteristics in a Two-Terminal Molecular Electronic Device

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We present a quantum mechanical tunneling model for electron transport through a molecular junction and address the model with the results of quantum chemical electronic structure calculations. The model gives insight into the origin of the substituent effect on the current versus applied voltage characteristics of molecular junctions.
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Keywords: CURRENT-VOLTAGE CHARACTERISTICS; MOLECULAR JUNCTION; QUANTUM CHEMICAL CALCULATIONS; SUBSTITUENT EFFECT; TUNNELING MODEL

Document Type: Communications

Affiliations: 1: Department of Chemistry and Biochemistry, Long Island University, Brooklyn, New York 11201, USA 2: Department of Chemistry, Drexel University, Philadelphia, Pennsylvania 19104, USA

Publication date: 2001-09-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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