Crystal Structure and Coexistence of Localized and Delocalized Electrons in Nb12O29

Authors: Llunell M.1; Alemany P.1; Canadell E.2

Source: Journal of Solid State Chemistry, Volume 149, Number 1, January 2000 , pp. 176-179(4)

Publisher: Academic Press

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Abstract:

The electronic structure of Nb12O29, the first member of the NbO2.5-x (0lexle0.083) family of phases, has been studied. It is suggested that in order to understand the coexistence of antiferromagnetism and metallic conductivity in this phase a new crystal structure determination is needed. Copyright 2000 Academic Press.

Language: English

Document Type: Research article

Affiliations: 1: Centre Especial de Recerca en Química Teòrica, Universitat de Barcelona, Diagonal 647, Barcelona, 08028, Spain 2: Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., Bellaterra, 08193, Spain

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