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Cogwheel Phase Cycling

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Abstract:

A new method for constructing phase cycles is described. The new schemes apply to experiments involving several consecutive coherence transfer steps. The radiofrequency phases of two or more irradiation blocks are incremented simultaneously, as opposed to the traditional “nested” scheme, in which the block phases are incremented independently. In many cases, the “cogwheel” phase cycles achieve the same selectivity as traditional phase cycles, using fewer steps. Significant time savings are achievable in a wide range of NMR experiments. © 2002 Elsevier Science (USA).

Document Type: Editorial

Affiliations: 1: Chemistry Department, Southampton University, SO17 1BJ, England 2: Physical Chemistry Division, Stockholm University, S-10691, Sweden

Publication date: April 1, 2002

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