Determination of Trace Amounts of Nickel, Manganese, Cobalt, and Zinc in Environmental Samples After Separation and Preconcentration by Use of Polyacrylic Acid/Alumina Sorbent

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Abstract:

Manganese, nickel, cobalt, and zinc are elements that appear together in many real samples. In this work, a simple, rapid, and sensitive method has been used for the simultaneous separation and preconcentration of trace amounts of these elements using water-soluble polyacrylic acid on alumina as a sorbent in a glass column system. A solution containing Mn, Ni, Co, and Zn was passed through the column at pH 7, and desorption was carried with 5.0 mL of 0.03 M nitric acid. Linearity was maintained between 0.255.0 103, 0.046.0 103, 0.108.0 103, and 0.0281.0 103 ng/mL for Ni, Mn, Co, and Zn, respectively, in the original solution. Eight replicate determinations of a mixture containing 1.0 g/mL of each of the elements in the final solution gave relative standard deviations of 1.4, 1.5, 2.4, and 1.2 for Ni, Mn, Co, and Zn, respectively. The sorption capacities for Mn (mg/g sorbent) obtained were 16.0 for Mn, 9.0 for Ni, 12.0 for Co, and 10.0 for Zn. By using 5.0 mL elution solution, preconcentration factors of 400, 500, 700, and 460 could be obtained for Ni, Mn, Zn, and Co, respectively.

Document Type: Research Article

Affiliations: Shahid Bahonar University of Kerman, Department of Chemistry, PO Box 76175-133Kerman, Iran.

Publication date: May 1, 2008

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  • The Journal of AOAC INTERNATIONAL publishes refereed papers and reviews in the fields of chemical, biological and toxicological analytical chemistry for the purpose of showcasing the most precise, accurate and sensitive methods for analysis of foods, food additives, supplements and contaminants, cosmetics, drugs, toxins, hazardous substances, pesticides, feeds, fertilizers and the environment available at that point in time. The scope of the Journal includes unpublished original research describing new analytical methods, techniques and applications; improved approaches to sampling, both in the field and the laboratory; better methods of preparing samples for analysis; collaborative studies substantiating the performance of a given method; statistical techniques for evaluating data. The Journal will also publish other articles of general interest to its audience, e.g., technical communications; cautionary notes; comments on techniques, apparatus, and reagents.
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