Thermally Grown ZnO Nanosheets for High Efficiency Dye-Sensitized Solar Cells

High efficiency dye-sensitized solar cells (DSSCs) were fabricated using ZnO nanosheet electrodes. ZnO nanosheets were synthesized on top of fluorine-doped tin oxide (FTO) glass using Zn(OAc)₂ as a precursor in the gold catalyzed chemical vapor deposition (CVD) method at a temperature of 800–900 °C. The synthesized materials were characterized by X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), and Raman and photoluminescence (PL) spectroscopy. Typical DSSCs with ZnO nanosheets achieved moderately good conversion efficiency  of ∼2.12% with short-circuit current density J_SC = 3.56 mA/cm², open-circuit voltage V_OC = 0.831 V, and fill factor FF = 71%. The high J_SC and  are attributed to high dye absorption through high surface ZnO nanosheets, which increased the light harvesting. The lower recombination rate was also observed in the ZnO nanosheet electrodes, resulting in high values of V_OC and FF in the DSSCs.